Bijvoet Ctr. for Biomol. Research, Dept. of Crystal and Struct. Chem., Utrecht University, Padualaan 8, 3584 CH Utrecht, Netherlands Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA Leiden, Netherlands
Riferimenti:
De Boer, J.L., Duisenberg, A.J.M., (1984) Acta Cryst., A40, pp. C-41
Bol, J.E., Driessen, W.L., Reedijk, J., (1995) J. Chem. Soc. Chem. Commun., pp. 1365-1366
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Kleywegt, G.J., Wiesmeijer, W.G.R., Van Driel, G.J., Driessen, W.L., Reedijk, J., Noordik, J.H., (1985) J. Chem. Soc. Dalton Trans., pp. 2177-2184
Le Page, Y., (1987) J. Appl. Cryst., 20, pp. 264-269
Sheldrick, G.M., (1985) SHELXS86. Program for the Solution of Crystal Structures, , University of Göttingen, Germany
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Spek, A.L., (1990) Acta Cryst., A46, pp. C-34
Spek, A.L., (1993) HELENA. Program for Data Reduction, , University of Utrecht, The Netherlands
Spek, A.L., (1996) PLUTON. Program for Molecular and Crystallo-graphic Graphics, , University of Utrecht, The Netherlands
De Boer, J. L., Duisenberg, A. J. M., (1984) Acta Cryst., A40, pp. C-41
Bol, J. E., Driessen, W. L., Reedijk, J., (1995) J. Chem. Soc. Chem. Commun., pp. 1365-1366
Claramunt, R. M., Domiano, P., Elguero, J., Lavandera, J. L., (1989) Bull. Soc. Chim. Fr., pp. 472-476
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Driessen, W. L., Haanstra, W. G., Reedijk, J., (1992) Acta Cryst., C48, pp. 1585-1587
(1989) CAD-4 Software. Version 5. 0, , Enraf-Nonius, Delft, The Netherlands
Haanstra, W. G., Driessen, W. L., De Graaff, R. A. G., Sebregts, G. C., Suriano, J., Reedijk, J., Turpeinen, U., Wood, J. S., (1991) Inorg. Chim. Acta, 189, pp. 243-251
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Kleywegt, G. J., Wiesmeijer, W. G. R., Van Driel, G. J., Driessen, W. L., Reedijk, J., Noordik, J. H., (1985) J. Chem. Soc. Dalton Trans., pp. 2177-2184
Sheldrick, G. M., (1985) SHELXS86. Program for the Solution of Crystal Structures, , University of G ttingen, Germany
Spek, A. L., (1988) J. Appl. Cryst., 21, pp. 578-579
Spek, A. L., (1990) Acta Cryst., A46, pp. C-34
Spek, A. L., (1993) HELENA. Program for Data Reduction, , University of Utrecht, The Netherlands
Spek, A. L., (1996) PLUTON. Program for Molecular and Crystallo-graphic Graphics, , University of Utrecht, The Netherlands
The title compound, [Ni2(NO3)2(C30H48N 10)(H2O)2]-(NO3) 2.2CH3OH, contains a doubly charged cation which lies across an inversion center. The hexadentate ligand N,N,N′,N′-tetrakis[2-(3,5-dimethyl-1-pyrazolyl)-ethyl]-1,2- ethylenediamine (tped) holds two NiII ions at a distance of 6.3721 (13) Å. A distorted octahedron around each NiII ion is denned by two pyrazole N atoms of tped at distances of 2.023 (4) and 2.048 (4) Å, one amine N atom of tped at a distance of 2.161 (4) Å, two O atoms of a chelating nitrate anion at distances of 2.144 (3) and 2.205 (4) Å, and a water O atom at a distance of 2.032 (4) Å. A one-dimensional hydrogen-bonding network running along the a axis connects the methanol molecule of crystallization to the nitrato and aqua ligands of different cations, and an aqua ligand to the non-coordinated nitrate ion. The structure is essentially isomorphous with the previously reported CuII analog [Driessen, Haanstra & Reedijk (1992). Acta Cryst. C48, 1585-1587], the main differences being that NO3 is involved in bidentate coordination to NiII and in a bifurcated hydrogen bond with methanol, whereas in the CuII complex, it is monodentate and only one of its O atoms hydrogen bonds to methanol.
236 Records (230 escludendo Abstract e Conferenze). Impact factor totale: 882.74 (869.826 escludendo Abstract e Conferenze). Impact factor a 5 anni totale: 1021.671 (1008.904 escludendo Abstract e Conferenze).
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