The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties
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The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties (82 visite)

Tabbì G, Driessen WL, Reedijk J, Veldman N, Spek AL

Inorg Chim Acta (ISSN: 0020-1693), 1999; 288(2): 239-243.



Tipo di articolo: Journal Article,

Impact factor: 1.295, Impact factor a 5 anni: 1.723

Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-0001093843&partnerID=40&md5=630286c35954d642b98e286762a61a95

Parole chiave: Crystal Structures, Multidentate Ligand Complexes, Nickel Complexes,

Affiliazioni:

Leiden Institute of Chemistry, Gorlaeus Labs., Leiden Univ., PO B., Leiden, Netherlands
Bijvoet Ctr. for Biomol. Research, Utrecht Univ., Padualaan 8, 3584 CH, Utrecht, Netherlands
Department of Chemical Sciences, Univ. Catania, Viale A. D., Catania, Italy


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The synthesis and characterization of the novel ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-[bis(imidazol-2-yl)methyl]-3-azapentane (bdpbiap) is described, together with a representative Ni(II) complex. The single crystal X-ray structure of [Ni(bdpbiap)NO3](NO3)·3H2O reveals the nickel ion to be in a distorted octahedral N4O2 geometry imposed by both the ligand and the coordinating didentate nitrate. One of the ligand imidazole groups is not coordinated to the metal ion. The solid-state ligand field electronic spectra confirm a distorted octahedral nickel(II) environment. The cyclic voltammogram shows unusually high reduction potentials for this nickel compound. © 1999 Elsevier Science S.A.
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5 Records (4 escludendo Abstract e Conferenze).
Impact factor totale: 15.922 (11.83 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 17.334 (12.797 escludendo Abstract e Conferenze).







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