The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties (178 views visite)
Inorg Chim Acta (ISSN: 0020-1693), 1999; 288(2): 239-243.
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Paper type Tipo di articolo: Journal Article,
Impact factor: 1.295, 5-year impact factor Impact factor a 5 anni: 1.723
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-0001093843&partnerID=40&md5=630286c35954d642b98e286762a61a95
Keywords Parole chiave: Crystal Structures, Multidentate Ligand Complexes, Nickel Complexes,
Affiliations Affiliazioni:
Leiden Institute of Chemistry, Gorlaeus Labs., Leiden Univ., PO B., Leiden, Netherlands
Bijvoet Ctr. for Biomol. Research, Utrecht Univ., Padualaan 8, 3584 CH, Utrecht, Netherlands
Department of Chemical Sciences, Univ. Catania, Viale A. D., Catania, Italy
References Riferimenti:
Trofimenko, S., (1986) Prog. Inorg. Chem., 34, p. 11
Bol, J.E., Driessen, W.L., Ho, R.Y.N., Maase, B., Que, L., Reedijk, J., (1997) Angew. Chem., Int. Ed. Engl., 36, p. 998
Tabbì, G., Driessen, W.L., Reedijk, J., Bonomo, R.P., Veldman, N., Spek, A.L., (1997) Inorg. Chem., 36, p. 1168
Bonomo, R.P., Conte, E., Marchelli, R., Santoro, A.M., Tabbì, G., (1994) J. Inorg. Biochem., 53, p. 127
Koolhaas, G.J.A.A., Driessen, W.L., Reedijk, J., Van Der Plas, J.L., De Graaff, R.A.G., Gatteschi, D., Kooijman, H., Spek, A.L., (1996) Inorg. Chem., 35, p. 1509
Higgins, S.J., (1997) Coord. Chem. Rev., 164, p. 503
Frausto Da Silva, J.J.R., Williams, R.J., (1991) The Inorganic Chemistry of Life, p. 400. , Oxford: Clarendon Press
Leigh, M.J.T., (1977) Synthesis, p. 459
Sorrell, T.N., Jameson, D.L., O'Connor, J., (1984) Inorg. Chem., 23, p. 190
Sawyer, D.T., Roberts, J.L., (1974) Experimental Electrochemistry for Chemistry, p. 54. , New York: Wiley
Spek, A.L., (1990) Acta Crystallogr., Sect. a, 46, p. 34
Beurskens, P.T., Admiraal, G., Beurskens, G., Bosman, W.P., Garcia-Granda, S., Gould, R.O., Smits, J.M.M., Smykalla, C., The DIRDIF Program System
Technical Report of the Crystallography Laboratory, , University of Nijmegen, The Netherlands
Sheldrick, G.M., (1993) SHELXL-93, Program for Crystal Structure Refinement, , University of Göttingen, Germany
Van Der Sluis, P., Spek, A.L., (1990) Acta Crystallogr., Sect. a, 46, p. 194
Spek, A.L., (1998) WINPL98, Interactive Molecular Graphics and Calculations Program for Windows, , University of Utrecht, The Netherlands
Paap, F., Bouwman, E., Driessen, W.L., De Graaf, R.A.G., Reedijk, J., (1985) J. Chem. Soc., Dalton Trans., p. 737
Kleywegt, G.J., Wiesmeijer, W.G.R., Van Driel, G.J., Driessen, W.L., Reedijk, J., (1985) J. Chem. Soc., Dalton Trans., p. 2177
Lever, A.B.P., (1984) Inorganic Electronic Spectroscopy, p. 816. , Amsterdam: Elsevier
Lever, A.B.P., (1968) J. Chem. Ed., 45, p. 711
Kitajima, N., Hikichi, S., Tanaka, M., Moro-Oka, Y., (1993) J. Am. Chem. Soc., 115, p. 5496
Nervi, C., (1998) Electrochemical Simulation Package Ver. 2.4, , University of Turin, locally written program
Zilbermann, I., Winnik, M., Sagiv, D., Rotman, A., Cohen, H., Meyerstein, D., (1995) Inorg. Chim. Acta, 240, p. 503
Inorg Chim Acta (ISSN: 0020-1693), 1999; 288(2): 239-243.
Export to Esporta in BibTeX Export to Esporta in EndNote
Paper type Tipo di articolo: Journal Article,
Impact factor: 1.295, 5-year impact factor Impact factor a 5 anni: 1.723
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-0001093843&partnerID=40&md5=630286c35954d642b98e286762a61a95
Keywords Parole chiave: Crystal Structures, Multidentate Ligand Complexes, Nickel Complexes,
Affiliations Affiliazioni:
Leiden Institute of Chemistry, Gorlaeus Labs., Leiden Univ., PO B., Leiden, Netherlands
Bijvoet Ctr. for Biomol. Research, Utrecht Univ., Padualaan 8, 3584 CH, Utrecht, Netherlands
Department of Chemical Sciences, Univ. Catania, Viale A. D., Catania, Italy
References Riferimenti:
Trofimenko, S., (1986) Prog. Inorg. Chem., 34, p. 11
Bol, J.E., Driessen, W.L., Ho, R.Y.N., Maase, B., Que, L., Reedijk, J., (1997) Angew. Chem., Int. Ed. Engl., 36, p. 998
Tabbì, G., Driessen, W.L., Reedijk, J., Bonomo, R.P., Veldman, N., Spek, A.L., (1997) Inorg. Chem., 36, p. 1168
Bonomo, R.P., Conte, E., Marchelli, R., Santoro, A.M., Tabbì, G., (1994) J. Inorg. Biochem., 53, p. 127
Koolhaas, G.J.A.A., Driessen, W.L., Reedijk, J., Van Der Plas, J.L., De Graaff, R.A.G., Gatteschi, D., Kooijman, H., Spek, A.L., (1996) Inorg. Chem., 35, p. 1509
Higgins, S.J., (1997) Coord. Chem. Rev., 164, p. 503
Frausto Da Silva, J.J.R., Williams, R.J., (1991) The Inorganic Chemistry of Life, p. 400. , Oxford: Clarendon Press
Leigh, M.J.T., (1977) Synthesis, p. 459
Sorrell, T.N., Jameson, D.L., O'Connor, J., (1984) Inorg. Chem., 23, p. 190
Sawyer, D.T., Roberts, J.L., (1974) Experimental Electrochemistry for Chemistry, p. 54. , New York: Wiley
Spek, A.L., (1990) Acta Crystallogr., Sect. a, 46, p. 34
Beurskens, P.T., Admiraal, G., Beurskens, G., Bosman, W.P., Garcia-Granda, S., Gould, R.O., Smits, J.M.M., Smykalla, C., The DIRDIF Program System
Technical Report of the Crystallography Laboratory, , University of Nijmegen, The Netherlands
Sheldrick, G.M., (1993) SHELXL-93, Program for Crystal Structure Refinement, , University of Göttingen, Germany
Van Der Sluis, P., Spek, A.L., (1990) Acta Crystallogr., Sect. a, 46, p. 194
Spek, A.L., (1998) WINPL98, Interactive Molecular Graphics and Calculations Program for Windows, , University of Utrecht, The Netherlands
Paap, F., Bouwman, E., Driessen, W.L., De Graaf, R.A.G., Reedijk, J., (1985) J. Chem. Soc., Dalton Trans., p. 737
Kleywegt, G.J., Wiesmeijer, W.G.R., Van Driel, G.J., Driessen, W.L., Reedijk, J., (1985) J. Chem. Soc., Dalton Trans., p. 2177
Lever, A.B.P., (1984) Inorganic Electronic Spectroscopy, p. 816. , Amsterdam: Elsevier
Lever, A.B.P., (1968) J. Chem. Ed., 45, p. 711
Kitajima, N., Hikichi, S., Tanaka, M., Moro-Oka, Y., (1993) J. Am. Chem. Soc., 115, p. 5496
Nervi, C., (1998) Electrochemical Simulation Package Ver. 2.4, , University of Turin, locally written program
Zilbermann, I., Winnik, M., Sagiv, D., Rotman, A., Cohen, H., Meyerstein, D., (1995) Inorg. Chim. Acta, 240, p. 503
The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties
The synthesis and characterization of the novel ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-[bis(imidazol-2-yl)methyl]-3-azapentane (bdpbiap) is described, together with a representative Ni(II) complex. The single crystal X-ray structure of [Ni(bdpbiap)NO3](NO3)·3H2O reveals the nickel ion to be in a distorted octahedral N4O2 geometry imposed by both the ligand and the coordinating didentate nitrate. One of the ligand imidazole groups is not coordinated to the metal ion. The solid-state ligand field electronic spectra confirm a distorted octahedral nickel(II) environment. The cyclic voltammogram shows unusually high reduction potentials for this nickel compound. © 1999 Elsevier Science S.A.
The synthesis and characterization of the novel ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-[bis(imidazol-2-yl)methyl]-3-azapentane (bdpbiap) is described, together with a representative Ni(II) complex. The single crystal X-ray structure of [Ni(bdpbiap)NO3](NO3)·3H2O reveals the nickel ion to be in a distorted octahedral N4O2 geometry imposed by both the ligand and the coordinating didentate nitrate. One of the ligand imidazole groups is not coordinated to the metal ion. The solid-state ligand field electronic spectra confirm a distorted octahedral nickel(II) environment. The cyclic voltammogram shows unusually high reduction potentials for this nickel compound. © 1999 Elsevier Science S.A.
The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties
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Impact factor totale: 22.273 (18.181 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 20.875 (16.338 escludendo Abstract e Conferenze).
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