Solvent-Free Synthesis of Modified Pectin Compounds Promoted by Microwave Irradiation (380 views visite)
Molecules (ISSN: 1420-3049, 1420-3049electronic, 1420-3049linking), 2012 Oct; 17(10): 12234-12242.
Export to Esporta in BibTeX Export to Esporta in EndNote
Paper type Tipo di articolo: Journal Article,
Impact factor: 2.428, 5-year impact factor Impact factor a 5 anni: 2.679
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-84868112194&partnerID=40&md5=26e6b641f5675e233bb9bd2040d2904f
Keywords Parole chiave: Green Chemistry, Microwave Irradiation, Pectin, Solvent-Free, Article, Infrared Spectroscopy, Microwave Radiation, Synthesis, Thermogravimetry, Fourier Transform Infrared,
Affiliations Affiliazioni:
*** IBB - CNR ***
Institute of Biostructures and Bioimages, National Research Council, 80138 Naples, Italy
Department of Industrial Engineering, University of Salerno, 84084 Fisciano (SA), Italy
References Riferimenti:
Tanaka, K., Toda, F., Solvent-free organic synthesis (2000) Chem. Rev., 100, pp. 1025-107
Lidstrom, P., Tierney, J., Wathey, B., Westman, J., Microwave assisted organic synthesis\\A review (2001) Tetrahedron, 57, pp. 9225-9283
Ravichandran, S., Karthikeyan, E., Microwave synthesis\\A potential tool for green chemistry (2011) Int. J. ChemTech Res., 3, pp. 466-470
Loupy, A., Solvent-free microwave organic synthesis as an efficient procedure for green chemistry (2004) C. R. Chimie, 7, pp. 103-112
Li, J., Zhang, L., Peng, F., Bian, J., Yuan, T., Xu, F., Sun, R., Microwave-assisted solvent-free acetylation of cellulose with acetic anhydride in the presence of iodine as a catalyst (2009) Molecules, 14, pp. 3551-3566
Varma, R.S., Solvent-free organic syntheses using supported reagents and microwave irradiation (1999) Green Chem., 1, pp. 43-55
Kappe, C.O., Controlled microwave heating in modern organic synthesis (2004) Angew. Chem. Int. Ed., 43, pp. 6250-6284
Monfregola, L., Bugatti, V., Amodeo, P., De Luca, S., Vittoria, V., Physical and water sorption properties of chemically modified pectin with an environmentally friendly process (2011) Biomacromolecules, 12, pp. 2311-2318
Monfregola, L., Leone, M., Vittoria, V., Amodeo, P., De Luca, S., Chemical modification of pectin: Environmental friendly process for new potential material development (2011) Polym. Chem., 2, pp. 800-804
Gandini, A., Polymers from renewable resources: A challenge for the future of macromolecular materials (2008) Macromolecules, 41, pp. 9491-9504
Williams, C.K., Hillmyer, M.A., Polymers from renewable resources: A perspective for a special issue of polymer reviews (2008) Polym. Rev., 48, pp. 1-10
Guilherme, M.R., Moia, T.A., Reis, A.V., Paulino, A.T., Rubira, A.F., Mattoso, L.H.C., Muniz, E.C., Tambourgi, E.B., Synthesis and water absorption transport mechanism of a pH sensitive polymer network structured on vinyl-functionalized pectin (2009) Biomacromolecules, 10, pp. 190-196
Junistia, L., Sugih, A.K., Manurung, R., Picchioni, F., Janssen, L.P.B.M., Heeres, H.J., Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants (2008) Starch/Stärke, 60, pp. 667-675
Sashiwa, H., Yajima, H., Aiba, S., Synthesis of a chitosan-dendrimer hybrid and its biodegradation (2003) Biomacromolecules, 4, pp. 1244-1249
Coffin, D.R., Fishman, M.L., Physical and mechanical properties of highly plasticized pectin/starch films (1994) J. Appl. Polym. Sci., 54, pp. 1311-1320
Kaplan, D.L., (1998) Biopolymers from Renewable Resources, , Springer-Verlag: Berlin/Heidelberg, Germany
Thakur, B.R., Singh, R.K., Handa, A.K., Chemistry and uses of pectin\\A review (1997) Crit. Rev. Food Sci. Nutr., 37, pp. 47-73
Mitchel, J.R., Hill, S.E., Ledward, D.A., (1998) Functional Properties of Food Macromolecules, 2nd Ed, , Aspen Publication: Gaithersburg, MA, USA
Zaleska, H., Ring, S.G., Tomasik, P., Apple pectin complexes with whey protein isolate (2000) Food Hydrocoll., 14, pp. 377-382
Synytsya, A., Copikova, J., Matejka, P., MacHovic, V., Fourier transform Raman and IR spectroscopy of pectins (2003) Carbohydr. Polym., 54, pp. 97-106
Filippov, M.P., Practical infrared spectroscopy of pectic substances (1992) Food Hydrocoll., 6, pp. 115-142
Kamnev, A.A., Ptitchkina, N.M., Ristic, M., Shkodina, O.G., Ignatov, V.V., (1995) Spectroscopy of Biological Molecules, pp. 445-446. , Merlin, J.C., Turrell, S., Huvenne, J.P., Eds. Kluwer: Dordrecht, The Netherlands
Zhbankov, R.G., Vibrational spectra and structure of mono-and polysaccharides (1992) J. Mol. Struct., 275, pp. 65-84
Matora, A.V., Korshunova, V.E., Shkodina, O.G., Zhemerichkin, D.A., Ptitchkina, N.M., Morris, E.R., The application of bacterial enzymes for extraction of pectin from pumpkin and sugar beet (1995) Food Hydrocoll., 9, pp. 43-46
Gnanasambandam, R., Proctor, A., Determination of pectin degree of esterification by diffuse reflectance Fourier transform infrared spectroscopy (2000) Food Chem., 68, pp. 327-332
Xin, J.Y., Wang, Y., Liu, T., Lin, K., Chang, L., Xia, C.G., Biosynthesis of corn starch palmitate by lipase Novozym 435 (2012) Int. J. Mol. Sci., 13, pp. 7226-7236
Lu, X., Luo, Z., Yu, S., Fu, X., Lipase-catalyzed synthesis of starch palmitate in mixed ionic liquids (2012) J. Agric. Food Chem., 60, pp. 9273-9279
Einhorn-Stoll, U., Kunzek, H., Thermoanalytical characterisation of processing-dependent structural changes and state transitions of citrus pectin (2009) Food Hydrocoll., 23, pp. 40-52
Varma, R. S., Solvent-free organic syntheses using supported reagents and microwave irradiation (1999) Green Chem., 1, pp. 43-55
Kappe, C. O., Controlled microwave heating in modern organic synthesis (2004) Angew. Chem. Int. Ed., 43, pp. 6250-6284
Williams, C. K., Hillmyer, M. A., Polymers from renewable resources: A perspective for a special issue of polymer reviews (2008) Polym. Rev., 48, pp. 1-10
Guilherme, M. R., Moia, T. A., Reis, A. V., Paulino, A. T., Rubira, A. F., Mattoso, L. H. C., Muniz, E. C., Tambourgi, E. B., Synthesis and water absorption transport mechanism of a pH sensitive polymer network structured on vinyl-functionalized pectin (2009) Biomacromolecules, 10, pp. 190-196
Coffin, D. R., Fishman, M. L., Physical and mechanical properties of highly plasticized pectin/starch films (1994) J. Appl. Polym. Sci., 54, pp. 1311-1320
Kaplan, D. L., (1998) Biopolymers from Renewable Resources, , Springer-Verlag: Berlin/Heidelberg, Germany
Thakur, B. R., Singh, R. K., Handa, A. K., Chemistry and uses of pectin\\A review (1997) Crit. Rev. Food Sci. Nutr., 37, pp. 47-73
Mitchel, J. R., Hill, S. E., Ledward, D. A., (1998) Functional Properties of Food Macromolecules, 2nd Ed, , Aspen Publication: Gaithersburg, MA, USA
Filippov, M. P., Practical infrared spectroscopy of pectic substances (1992) Food Hydrocoll., 6, pp. 115-142
Kamnev, A. A., Ptitchkina, N. M., Ristic, M., Shkodina, O. G., Ignatov, V. V., (1995) Spectroscopy of Biological Molecules, pp. 445-446. , Merlin, J. C., Turrell, S., Huvenne, J. P., Eds. Kluwer: Dordrecht, The Netherlands
Zhbankov, R. G., Vibrational spectra and structure of mono-and polysaccharides (1992) J. Mol. Struct., 275, pp. 65-84
Matora, A. V., Korshunova, V. E., Shkodina, O. G., Zhemerichkin, D. A., Ptitchkina, N. M., Morris, E. R., The application of bacterial enzymes for extraction of pectin from pumpkin and sugar beet (1995) Food Hydrocoll., 9, pp. 43-46
Xin, J. Y., Wang, Y., Liu, T., Lin, K., Chang, L., Xia, C. G., Biosynthesis of corn starch palmitate by lipase Novozym 435 (2012) Int. J. Mol. Sci., 13, pp. 7226-7236
Molecules (ISSN: 1420-3049, 1420-3049electronic, 1420-3049linking), 2012 Oct; 17(10): 12234-12242.
Export to Esporta in BibTeX Export to Esporta in EndNote
Paper type Tipo di articolo: Journal Article,
Impact factor: 2.428, 5-year impact factor Impact factor a 5 anni: 2.679
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-84868112194&partnerID=40&md5=26e6b641f5675e233bb9bd2040d2904f
Keywords Parole chiave: Green Chemistry, Microwave Irradiation, Pectin, Solvent-Free, Article, Infrared Spectroscopy, Microwave Radiation, Synthesis, Thermogravimetry, Fourier Transform Infrared,
Affiliations Affiliazioni:
*** IBB - CNR ***
Institute of Biostructures and Bioimages, National Research Council, 80138 Naples, Italy
Department of Industrial Engineering, University of Salerno, 84084 Fisciano (SA), Italy
References Riferimenti:
Tanaka, K., Toda, F., Solvent-free organic synthesis (2000) Chem. Rev., 100, pp. 1025-107
Lidstrom, P., Tierney, J., Wathey, B., Westman, J., Microwave assisted organic synthesis\\A review (2001) Tetrahedron, 57, pp. 9225-9283
Ravichandran, S., Karthikeyan, E., Microwave synthesis\\A potential tool for green chemistry (2011) Int. J. ChemTech Res., 3, pp. 466-470
Loupy, A., Solvent-free microwave organic synthesis as an efficient procedure for green chemistry (2004) C. R. Chimie, 7, pp. 103-112
Li, J., Zhang, L., Peng, F., Bian, J., Yuan, T., Xu, F., Sun, R., Microwave-assisted solvent-free acetylation of cellulose with acetic anhydride in the presence of iodine as a catalyst (2009) Molecules, 14, pp. 3551-3566
Varma, R.S., Solvent-free organic syntheses using supported reagents and microwave irradiation (1999) Green Chem., 1, pp. 43-55
Kappe, C.O., Controlled microwave heating in modern organic synthesis (2004) Angew. Chem. Int. Ed., 43, pp. 6250-6284
Monfregola, L., Bugatti, V., Amodeo, P., De Luca, S., Vittoria, V., Physical and water sorption properties of chemically modified pectin with an environmentally friendly process (2011) Biomacromolecules, 12, pp. 2311-2318
Monfregola, L., Leone, M., Vittoria, V., Amodeo, P., De Luca, S., Chemical modification of pectin: Environmental friendly process for new potential material development (2011) Polym. Chem., 2, pp. 800-804
Gandini, A., Polymers from renewable resources: A challenge for the future of macromolecular materials (2008) Macromolecules, 41, pp. 9491-9504
Williams, C.K., Hillmyer, M.A., Polymers from renewable resources: A perspective for a special issue of polymer reviews (2008) Polym. Rev., 48, pp. 1-10
Guilherme, M.R., Moia, T.A., Reis, A.V., Paulino, A.T., Rubira, A.F., Mattoso, L.H.C., Muniz, E.C., Tambourgi, E.B., Synthesis and water absorption transport mechanism of a pH sensitive polymer network structured on vinyl-functionalized pectin (2009) Biomacromolecules, 10, pp. 190-196
Junistia, L., Sugih, A.K., Manurung, R., Picchioni, F., Janssen, L.P.B.M., Heeres, H.J., Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants (2008) Starch/Stärke, 60, pp. 667-675
Sashiwa, H., Yajima, H., Aiba, S., Synthesis of a chitosan-dendrimer hybrid and its biodegradation (2003) Biomacromolecules, 4, pp. 1244-1249
Coffin, D.R., Fishman, M.L., Physical and mechanical properties of highly plasticized pectin/starch films (1994) J. Appl. Polym. Sci., 54, pp. 1311-1320
Kaplan, D.L., (1998) Biopolymers from Renewable Resources, , Springer-Verlag: Berlin/Heidelberg, Germany
Thakur, B.R., Singh, R.K., Handa, A.K., Chemistry and uses of pectin\\A review (1997) Crit. Rev. Food Sci. Nutr., 37, pp. 47-73
Mitchel, J.R., Hill, S.E., Ledward, D.A., (1998) Functional Properties of Food Macromolecules, 2nd Ed, , Aspen Publication: Gaithersburg, MA, USA
Zaleska, H., Ring, S.G., Tomasik, P., Apple pectin complexes with whey protein isolate (2000) Food Hydrocoll., 14, pp. 377-382
Synytsya, A., Copikova, J., Matejka, P., MacHovic, V., Fourier transform Raman and IR spectroscopy of pectins (2003) Carbohydr. Polym., 54, pp. 97-106
Filippov, M.P., Practical infrared spectroscopy of pectic substances (1992) Food Hydrocoll., 6, pp. 115-142
Kamnev, A.A., Ptitchkina, N.M., Ristic, M., Shkodina, O.G., Ignatov, V.V., (1995) Spectroscopy of Biological Molecules, pp. 445-446. , Merlin, J.C., Turrell, S., Huvenne, J.P., Eds. Kluwer: Dordrecht, The Netherlands
Zhbankov, R.G., Vibrational spectra and structure of mono-and polysaccharides (1992) J. Mol. Struct., 275, pp. 65-84
Matora, A.V., Korshunova, V.E., Shkodina, O.G., Zhemerichkin, D.A., Ptitchkina, N.M., Morris, E.R., The application of bacterial enzymes for extraction of pectin from pumpkin and sugar beet (1995) Food Hydrocoll., 9, pp. 43-46
Gnanasambandam, R., Proctor, A., Determination of pectin degree of esterification by diffuse reflectance Fourier transform infrared spectroscopy (2000) Food Chem., 68, pp. 327-332
Xin, J.Y., Wang, Y., Liu, T., Lin, K., Chang, L., Xia, C.G., Biosynthesis of corn starch palmitate by lipase Novozym 435 (2012) Int. J. Mol. Sci., 13, pp. 7226-7236
Lu, X., Luo, Z., Yu, S., Fu, X., Lipase-catalyzed synthesis of starch palmitate in mixed ionic liquids (2012) J. Agric. Food Chem., 60, pp. 9273-9279
Einhorn-Stoll, U., Kunzek, H., Thermoanalytical characterisation of processing-dependent structural changes and state transitions of citrus pectin (2009) Food Hydrocoll., 23, pp. 40-52
Varma, R. S., Solvent-free organic syntheses using supported reagents and microwave irradiation (1999) Green Chem., 1, pp. 43-55
Kappe, C. O., Controlled microwave heating in modern organic synthesis (2004) Angew. Chem. Int. Ed., 43, pp. 6250-6284
Williams, C. K., Hillmyer, M. A., Polymers from renewable resources: A perspective for a special issue of polymer reviews (2008) Polym. Rev., 48, pp. 1-10
Guilherme, M. R., Moia, T. A., Reis, A. V., Paulino, A. T., Rubira, A. F., Mattoso, L. H. C., Muniz, E. C., Tambourgi, E. B., Synthesis and water absorption transport mechanism of a pH sensitive polymer network structured on vinyl-functionalized pectin (2009) Biomacromolecules, 10, pp. 190-196
Coffin, D. R., Fishman, M. L., Physical and mechanical properties of highly plasticized pectin/starch films (1994) J. Appl. Polym. Sci., 54, pp. 1311-1320
Kaplan, D. L., (1998) Biopolymers from Renewable Resources, , Springer-Verlag: Berlin/Heidelberg, Germany
Thakur, B. R., Singh, R. K., Handa, A. K., Chemistry and uses of pectin\\A review (1997) Crit. Rev. Food Sci. Nutr., 37, pp. 47-73
Mitchel, J. R., Hill, S. E., Ledward, D. A., (1998) Functional Properties of Food Macromolecules, 2nd Ed, , Aspen Publication: Gaithersburg, MA, USA
Filippov, M. P., Practical infrared spectroscopy of pectic substances (1992) Food Hydrocoll., 6, pp. 115-142
Kamnev, A. A., Ptitchkina, N. M., Ristic, M., Shkodina, O. G., Ignatov, V. V., (1995) Spectroscopy of Biological Molecules, pp. 445-446. , Merlin, J. C., Turrell, S., Huvenne, J. P., Eds. Kluwer: Dordrecht, The Netherlands
Zhbankov, R. G., Vibrational spectra and structure of mono-and polysaccharides (1992) J. Mol. Struct., 275, pp. 65-84
Matora, A. V., Korshunova, V. E., Shkodina, O. G., Zhemerichkin, D. A., Ptitchkina, N. M., Morris, E. R., The application of bacterial enzymes for extraction of pectin from pumpkin and sugar beet (1995) Food Hydrocoll., 9, pp. 43-46
Xin, J. Y., Wang, Y., Liu, T., Lin, K., Chang, L., Xia, C. G., Biosynthesis of corn starch palmitate by lipase Novozym 435 (2012) Int. J. Mol. Sci., 13, pp. 7226-7236
Solvent-Free Synthesis of Modified Pectin Compounds Promoted by Microwave Irradiation
Microwave-assisted solvent-free modification of pectin was successfully accomplished, consisting in the esterification of several fatty acids by pectin alcoholic functions. The reaction was performed by simply mixing the reagents with a catalytic amount of the inorganic base (potassium carbonate) and irradiating the obtained mixture with microwaves for a short time (3-6 min). The replacement of the traditional heating with a microwave source allowed the development of a new synthetic protocol which provided increased yield of the final products, since it eliminates the small amount of degraded polysaccharide produced during traditional oil bath heating. The desired esters were fully characterized by FT-IR spectroscopy and thermogravimetric analysis.
Microwave-assisted solvent-free modification of pectin was successfully accomplished, consisting in the esterification of several fatty acids by pectin alcoholic functions. The reaction was performed by simply mixing the reagents with a catalytic amount of the inorganic base (potassium carbonate) and irradiating the obtained mixture with microwaves for a short time (3-6 min). The replacement of the traditional heating with a microwave source allowed the development of a new synthetic protocol which provided increased yield of the final products, since it eliminates the small amount of degraded polysaccharide produced during traditional oil bath heating. The desired esters were fully characterized by FT-IR spectroscopy and thermogravimetric analysis.
Solvent-Free Synthesis of Modified Pectin Compounds Promoted by Microwave Irradiation
Solvent-Free Synthesis of Modified Pectin Compounds Promoted by Microwave Irradiation
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Impact Factor: 1.311
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Rossi F, Saviano M, Di Blasio B, Zanotti G, Maione AM, Tancredi T, Pedone C
BIOACTIVE PEPTIDES - SOLID-STATE, SOLUTION AND MOLECULAR-DYNAMICS STUDIES OF A CYCLOLINOPEPTIDE-A RELATED CYSTINYL CYCLOPENTAPEPTIDE (437 visite)
Biopolymers (ISSN: 0006-3525, 0006-6352, 0006-3525print), 1994 Feb; 34(2): 273-284.
Impact Factor: 2.425
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23 Records (22 escludendo Abstract e Conferenze).
Impact factor totale: 90.252 (85.901 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 94.86 (90.477 escludendo Abstract e Conferenze).
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Altug C, Gunes H, Nocentini A, Monti SM, Buonanno M, Supuran CT
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Anal Bioanal Chem (ISSN: 1618-2642), 2013 Feb; 405(6): 1833-1843.
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Abbate M, Casella G, Fiore T, Grasso G, Pellerito C, Scopelliti M, Spinella A, Pellerito L
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J Organomet Chem (ISSN: 0022-328x), 2010 May 1; 695(9): 1405-1413.
Impact Factor: 2.205
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Scir A, Pedone E, Ausili A, Saviano M, Baldassarre M, Bertoli E, Bartolucci S, Tanfani F
* High hydrostatic pressure-induced conformational changes in protein disulfide oxidoreductase from the hyperthermophilic archaeon Pyrococcus furiosus. A Fourier-transform infrared spectroscopic study (330 visite)
Molecular Biosystems (ISSN: 1742-206x), 2010; 6(10): 2015-2022.
Impact Factor: 3.825
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Arnesano F, Scintilla S, Calò V, Bonfrate E, Ingrosso C, Losacco M, Pellegrino T, Rizzarelli E, Natile G
* Copper-triggered aggregation of ubiquitin (510 visite)
Plosone (ISSN: 1932-6203, 1932-6203electronic), 2009 Sep 16; 4(9): e7052-e7052.
Impact Factor: 4.351
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Messere A, Fabbri E, Borgatti M, Gambari R, Di Blasio B, Pedone C, Romanelli A
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Impact Factor: 3.663
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Impact Factor: 1.801
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Mannini R, Rivieccio V, D'Auria S, Tanfani F, Ausili A, Pedone C, Grimaldi G, Facchiano A
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Impact Factor: 3.73
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Pedone E, Saviano M, Bartolucci S, Rossi M, Ausili A, Scire A, Bertoli E, Tanfani F
* Temperature-, SDS-, and pH-induced conformational changes in protein disulfide oxidoreductase from the archaeon Pyrococcus furiosus: A dynamic simulation and fourier transform infrared spectroscopic study (294 visite)
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Pedone E, Bartolucci S, Rossi M, Pierfederici FM, Scire A, Cacciamani T, Tanfani F
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Biochem J (ISSN: 0264-6021, 1470-8728electronic, 0264-6021linking), 2003 Sep 1; 373: 875-883.
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Formaggio F, Crisma M, Toniolo C, Broxterman QB, Kaptein B, Corbier C, Saviano M, Palladino P, Benedetti E
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Macromolecules (ISSN: 0024-9297), 2003; 36(21): 8164-8170.
Impact Factor: 3.621
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Peggion C, Formaggio F, Crisma M, Toniolo C, Jimenez AI, Cativiela C, Kaptein B, Broxterman QB, Saviano M, Benedetti E
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Biopolymers (ISSN: 0006-3525, 0006-6352, 0006-3525print), 2003; 68(2): 178-191.
Impact Factor: 2.733
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Formaggio F, Bonchio M, Crisma M, Peggion C, Mezzato S, Polese A, Barazza A, Antonello S, Maran F, Broxterman QB, Kaptein B, Kamphuis J, Vitale RM, Saviano M, Benedetti E, Toniolo C
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Chemistry (ISSN: 0947-6539, 1521-3765, 1521-3765electronic), 2002; 8(1): [d]84-93.
Impact Factor: 4.238
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Gatos M, Formaggio F, Crisma M, Valle G, Toniolo C, Bonora GM, Saviano M, Iacovino R, Menchise V, Galdiero S, Pedone C, Benedetti E
Conformational Characterization Of Peptides Rich In The Cycloaliphatic C Alpha, Alpha-Disubstituted Glycine 1-Aminocyclononane-1-Carboxylic Acid (404 visite)
J Pept Sci (ISSN: 1075-2617, 1099-1387, 1075-2617print), 1997 Sep; 3(5): 367-382.
Impact Factor: 1.311
Dettagli Esporta in BibTeX Esporta in EndNote
Rossi F, Saviano M, Di Blasio B, Zanotti G, Maione AM, Tancredi T, Pedone C
BIOACTIVE PEPTIDES - SOLID-STATE, SOLUTION AND MOLECULAR-DYNAMICS STUDIES OF A CYCLOLINOPEPTIDE-A RELATED CYSTINYL CYCLOPENTAPEPTIDE (437 visite)
Biopolymers (ISSN: 0006-3525, 0006-6352, 0006-3525print), 1994 Feb; 34(2): 273-284.
Impact Factor: 2.425
Dettagli Esporta in BibTeX Esporta in EndNote
23 Records (22 escludendo Abstract e Conferenze).
Impact factor totale: 90.252 (85.901 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 94.86 (90.477 escludendo Abstract e Conferenze).
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