The Role of the Amino Protecting Group during Parahydrogenation of Protected Dehydroamino Acids (193 views visite)
J Phys Chem A (ISSN: 1089-5639, 1520-5215electronic), 2015 Nov 19; 119(46): 11271-11279.
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Paper type Tipo di articolo: Abstract, Journal Article,
Impact factor: 2.883, 5-year impact factor Impact factor a 5 anni: 2.709
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Keywords Parole chiave: Not available. Non disponibili.
Affiliations Affiliazioni:
*** IBB - CNR ***
Department of Molecular Biotechnologies and Health Sciences, University of Torino , Via Nizza 52, 10126 Torino, Italy.,
References Riferimenti:
Not available. Non disponibili.
J Phys Chem A (ISSN: 1089-5639, 1520-5215electronic), 2015 Nov 19; 119(46): 11271-11279.
Export to Esporta in BibTeX Export to Esporta in EndNote
Paper type Tipo di articolo: Abstract, Journal Article,
Impact factor: 2.883, 5-year impact factor Impact factor a 5 anni: 2.709
Url: Not available. Non disponibile.
Keywords Parole chiave: Not available. Non disponibili.
Affiliations Affiliazioni:
*** IBB - CNR ***
Department of Molecular Biotechnologies and Health Sciences, University of Torino , Via Nizza 52, 10126 Torino, Italy.,
References Riferimenti:
Not available. Non disponibili.
The Role of the Amino Protecting Group during Parahydrogenation of Protected Dehydroamino Acids
A series of dehydroamino acids endowed with different protective groups at the amino and carboxylate moieties and with different substituents at the double bond have been reacted with parahydrogen. The observed ParaHydrogen Induced Polarization (PHIP) effects in the (1)H NMR spectra are strongly dependent on the amino protecting group. DFT calculations allowed us to establish a relationship between the structures of the reaction intermediates (whose energies depend on the amido substitution) and the observed PHIP patterns.
A series of dehydroamino acids endowed with different protective groups at the amino and carboxylate moieties and with different substituents at the double bond have been reacted with parahydrogen. The observed ParaHydrogen Induced Polarization (PHIP) effects in the (1)H NMR spectra are strongly dependent on the amino protecting group. DFT calculations allowed us to establish a relationship between the structures of the reaction intermediates (whose energies depend on the amido substitution) and the observed PHIP patterns.
The Role of the Amino Protecting Group during Parahydrogenation of Protected Dehydroamino Acids
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The Role of the Amino Protecting Group during Parahydrogenation of Protected Dehydroamino Acids
Roviello GN, Gröschel S, Pedone C, Diederichsen U
* Synthesis of novel MMT/acyl-protected nucleo alanine monomers for the preparation of DNA/alanyl-PNA chimeras (370 visite)
Amino Acids (ISSN: 1438-2199, 0939-4451, 1438-2199electronic), 2010 May; 38(5): 1301-1309.
Impact Factor: 4.106
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1 Records (1 escludendo Abstract e Conferenze).
Impact factor totale: 4.106 (4.106 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 3.541 (3.541 escludendo Abstract e Conferenze).
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Roviello GN, Gröschel S, Pedone C, Diederichsen U
* Synthesis of novel MMT/acyl-protected nucleo alanine monomers for the preparation of DNA/alanyl-PNA chimeras (370 visite)
Amino Acids (ISSN: 1438-2199, 0939-4451, 1438-2199electronic), 2010 May; 38(5): 1301-1309.
Impact Factor: 4.106
Dettagli Esporta in BibTeX Esporta in EndNote
1 Records (1 escludendo Abstract e Conferenze).
Impact factor totale: 4.106 (4.106 escludendo Abstract e Conferenze).
Impact factor a 5 anni totale: 3.541 (3.541 escludendo Abstract e Conferenze).
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