Department of Chemical Science, University of Catania, viale A. Doria, 6, 95125 Catania, Italy CNR, Ist. di Biostrutture e Bioimmagini, Sezione di Catania, viale A. Doria, 6, 95125 Catania, Italy
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Ligand exchange chiral separations by cyclodextrin derivatives in capillary electrophoresis
A β-cyclodextrin substituted by an imidazole-bound histamine (CDmh) was successfully used to separate underivatised tryptophan racemate in capillary electrophoresis in the presence of copper(II) ion by the ligand exchange mechanism. To the best of our knowledge, this is the first example of a cyciodextrin derivative behaving as the first coordination sphere ligand in the complex added to the background electrolyte (BGE).
Ligand exchange chiral separations by cyclodextrin derivatives in capillary electrophoresis
258 Records (246 escludendo Abstract e Conferenze). Impact factor totale: 906.297 (868.473 escludendo Abstract e Conferenze). Impact factor a 5 anni totale: 958.372 (915.002 escludendo Abstract e Conferenze).
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