Institute of Biostructures and Bioimaging, National Research Council, 80134 Naples, Italy., Department of Chemistry and Biochemistry, University of Colorado , Boulder, Colorado 80309, United States.,
References: Not available.
Solid-Phase S-Alkylation Promoted by Molecular Sieves
A solid-phase S-alkylation procedure to introduce chemical modification on the cysteine sulfhydryl group of a peptidyl resin is reported. The reaction is promoted by activated molecular sieves and consists of a solid-solid process, since both the catalyst and the substrate are in a solid state. The procedure was revealed to be efficient and versatile, particularly when used in combination with the solution S-alkylation approach, allowing for the introduction of different molecular diversities on the same peptide molecule.
Solid-Phase S-Alkylation Promoted by Molecular Sieves
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