Selective sensing of Hg2+ by a proton-ionizable calix[4]arene fluoroionophore (347 views)
Anal Bioanal Chem (ISSN: 1618-2642), 2013 Jan; 405(2-3): 1133-1137.
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Paper type: Journal Article,
Impact factor: 3.578, 5-year impact factor: 3.744
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-84873738355&partnerID=40&md5=cfb62c9c877c4354c1303d7e8ced56b5
Keywords: Calixarenes, Fluorescent Sensor, Heavy Metals, Mercury, Selective Detection, Calix[4]arenes, Fluorogenics, Fluoroionophores, Low Concentration Levels, Mercury-Sensing, Mixed Solvent, Selective Sensing, Ligands, Mercury (metal), Metal Ions, Phenols, Positive Ions, Protons, Fluorescent Dye, Article, Chemistry, Equipment, Evaluation, Genetic Procedures, Methodology, Water Pollutant, Biosensing Techniques, Chemical, Calix [4] Arenes,
Affiliations:
*** IBB - CNR ***
Dipartimento di Scienze Chimiche, Università Degli Studi di Catania, Viale Andrea Doria 6, Catania 95125, Italy
Istituto di Biostrutture e Bioimmagini, UOS Catania, CNR, Viale A. Doria 6, Catania 95125, Italy
Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409, United States
References:
Hutchinson, T.C., Meema, K.M., (1987) Lead, Mercury, Cadmium and Arsenic in the Environment, , Wiley New Yor
Gadd, G.M., Heavy metal pollutants: Environmental and biotechnological aspects (2000) Encyclopedia of Microbiology, , J. Lederberg (eds). 2 Academic San Diego
Ferguson, J.E., (1990) The Heavy Elements: Environmental Impact and Health Effects, , Pergamon Oxford
Boening, D.W., (2000) Chemosphere, 40, pp. 1335-1351. , 10.1016/S0045-6535(99)00283-0 1:CAS:528:DC%2BD3cXit1yru7k%3D
Harris, H.H., Pickering, I.J., George, G.N., (2003) Science, 301, p. 1203. , 10.1126/science.1085941 1:CAS:528:DC%2BD3sXmvFejurs%3D
Selid, P.D., Xu, H., Collins, E.M., Striped Face-Collins, M., Zhao, J.X., (2009) Sensors, 9, pp. 5446-5459. , 10.3390/s90705446 1:CAS:528:DC%2BD1MXoslSlsL0%3D
Nolan, E.M., Lippard, S.J., (2008) Chem Rev, 108, pp. 3443-3480. , 10.1021/cr068000q 1:CAS:528:DC%2BD1cXovFygurY%3D
Leray, I., Valeur, B., (2009) Eur J Inorg Chem, 24, pp. 3525-3535. , 10.1002/ejic.200900386
Ocak, U., Ocak, M., Bartsch, R.A., (2012) Inorg Chim Acta, 381, pp. 44-57. , 10.1016/j.ica.2011.10.041 1:CAS:528:DC%2BC38XitFGhur8%3D
Talanova, G.G., Hwang, H.S., Talanov, V.S., Bartsch, R.A., (1998) J Chem Soc Chem Commun, pp. 1329-1330
Sgarlata, C., Arena, G., Longo, E., Zhang, D., Yang, Y., Bartsch, R.A., (2008) J Membr Sci, 323, pp. 444-451. , 10.1016/j.memsci.2008.07.004 1:CAS:528:DC%2BD1cXhtVCgu73E
Talanova, G.G., Talanov, V.S., Gorbunova, M.G., Hwang, H.S., Bartsch, R.A., (2002) J Chem Soc Perkin Trans, 2 (12), pp. 2072-2077
Vogel, A.I., (1961) Quantitative Inorganic Analysis, , Longmans London
Gans, P., Sabatini, A., Vacca, A., (1996) Talanta, 43, pp. 1739-1753. , 10.1016/0039-9140(96)01958-3 1:CAS:528:DyaK28XlvVWrsb0%3D
Lide, D.R., (1990) Handbook of Chemistry and Physics, , 71 CRC Boston
Pearson, R.G., (1963) J Am Chem Soc, 85, pp. 3533-3543. , 10.1021/ja00905a001 1:CAS:528:DyaF2cXksV0%3D
Harris, D., (2007) Quantitative Chemical Analysis, , 7 Freeman New York Section 5-2
Babic, S., Horvat, A.J.M., Pavlovic, D.M., Kastelan-Macan, M., (2007) Trends Anal Chem, 26, pp. 1043-1061. , 10.1016/j.trac.2007.09.004 1:CAS:528:DC%2BD2sXhtlynsbjP
Fernandez, F.A., Bartsch, R.A., Arnaud-Neu, F., Hubscher-Bruder, V., Michel, S., (2010) ARKIVOC, 7, pp. 191-202
Metivier, R., Leray, I., Valeur, B., (2004) Chem Eur J, 10, pp. 4480-4490. , 10.1002/chem.200400259 1:CAS:528:DC%2BD2cXotFyqt74%3D
Bhalla, V., Kumar, R., Kumar, M., Dhir, A., (2007) Tetrahedron, 63, pp. 11153-11159. , 10.1016/j.tet.2007.08.021 1:CAS:528:DC%2BD2sXhtFSisLbL
Hutchinson, T. C., Meema, K. M., (1987) Lead, Mercury, Cadmium and Arsenic in the Environment, , Wiley New Yor
Gadd, G. M., Heavy metal pollutants: Environmental and biotechnological aspects (2000) Encyclopedia of Microbiology, , J. Lederberg (eds). 2 Academic San Diego
Ferguson, J. E., (1990) The Heavy Elements: Environmental Impact and Health Effects, , Pergamon Oxford
Boening, D. W., (2000) Chemosphere, 40, pp. 1335-1351. , 10. 1016/S0045-6535 (99) 00283-0 1: CAS: 528: DC%2BD3cXit1yru7k%3D
Harris, H. H., Pickering, I. J., George, G. N., (2003) Science, 301, p. 1203. , 10. 1126/science. 1085941 1: CAS: 528: DC%2BD3sXmvFejurs%3D
Selid, P. D., Xu, H., Collins, E. M., Striped Face-Collins, M., Zhao, J. X., (2009) Sensors, 9, pp. 5446-5459. , 10. 3390/s90705446 1: CAS: 528: DC%2BD1MXoslSlsL0%3D
Nolan, E. M., Lippard, S. J., (2008) Chem Rev, 108, pp. 3443-3480. , 10. 1021/cr068000q 1: CAS: 528: DC%2BD1cXovFygurY%3D
Talanova, G. G., Hwang, H. S., Talanov, V. S., Bartsch, R. A., (1998) J Chem Soc Chem Commun, pp. 1329-1330
Talanova, G. G., Talanov, V. S., Gorbunova, M. G., Hwang, H. S., Bartsch, R. A., (2002) J Chem Soc Perkin Trans, 2 (12), pp. 2072-2077
Vogel, A. I., (1961) Quantitative Inorganic Analysis, , Longmans London
Lide, D. R., (1990) Handbook of Chemistry and Physics, , 71 CRC Boston
Pearson, R. G., (1963) J Am Chem Soc, 85, pp. 3533-3543. , 10. 1021/ja00905a001 1: CAS: 528: DyaF2cXksV0%3D
Fernandez, F. A., Bartsch, R. A., Arnaud-Neu, F., Hubscher-Bruder, V., Michel, S., (2010) ARKIVOC, 7, pp. 191-202
Anal Bioanal Chem (ISSN: 1618-2642), 2013 Jan; 405(2-3): 1133-1137.
Export to BibTeX Export to EndNote
Paper type: Journal Article,
Impact factor: 3.578, 5-year impact factor: 3.744
Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-84873738355&partnerID=40&md5=cfb62c9c877c4354c1303d7e8ced56b5
Keywords: Calixarenes, Fluorescent Sensor, Heavy Metals, Mercury, Selective Detection, Calix[4]arenes, Fluorogenics, Fluoroionophores, Low Concentration Levels, Mercury-Sensing, Mixed Solvent, Selective Sensing, Ligands, Mercury (metal), Metal Ions, Phenols, Positive Ions, Protons, Fluorescent Dye, Article, Chemistry, Equipment, Evaluation, Genetic Procedures, Methodology, Water Pollutant, Biosensing Techniques, Chemical, Calix [4] Arenes,
Affiliations:
*** IBB - CNR ***
Dipartimento di Scienze Chimiche, Università Degli Studi di Catania, Viale Andrea Doria 6, Catania 95125, Italy
Istituto di Biostrutture e Bioimmagini, UOS Catania, CNR, Viale A. Doria 6, Catania 95125, Italy
Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409, United States
References:
Hutchinson, T.C., Meema, K.M., (1987) Lead, Mercury, Cadmium and Arsenic in the Environment, , Wiley New Yor
Gadd, G.M., Heavy metal pollutants: Environmental and biotechnological aspects (2000) Encyclopedia of Microbiology, , J. Lederberg (eds). 2 Academic San Diego
Ferguson, J.E., (1990) The Heavy Elements: Environmental Impact and Health Effects, , Pergamon Oxford
Boening, D.W., (2000) Chemosphere, 40, pp. 1335-1351. , 10.1016/S0045-6535(99)00283-0 1:CAS:528:DC%2BD3cXit1yru7k%3D
Harris, H.H., Pickering, I.J., George, G.N., (2003) Science, 301, p. 1203. , 10.1126/science.1085941 1:CAS:528:DC%2BD3sXmvFejurs%3D
Selid, P.D., Xu, H., Collins, E.M., Striped Face-Collins, M., Zhao, J.X., (2009) Sensors, 9, pp. 5446-5459. , 10.3390/s90705446 1:CAS:528:DC%2BD1MXoslSlsL0%3D
Nolan, E.M., Lippard, S.J., (2008) Chem Rev, 108, pp. 3443-3480. , 10.1021/cr068000q 1:CAS:528:DC%2BD1cXovFygurY%3D
Leray, I., Valeur, B., (2009) Eur J Inorg Chem, 24, pp. 3525-3535. , 10.1002/ejic.200900386
Ocak, U., Ocak, M., Bartsch, R.A., (2012) Inorg Chim Acta, 381, pp. 44-57. , 10.1016/j.ica.2011.10.041 1:CAS:528:DC%2BC38XitFGhur8%3D
Talanova, G.G., Hwang, H.S., Talanov, V.S., Bartsch, R.A., (1998) J Chem Soc Chem Commun, pp. 1329-1330
Sgarlata, C., Arena, G., Longo, E., Zhang, D., Yang, Y., Bartsch, R.A., (2008) J Membr Sci, 323, pp. 444-451. , 10.1016/j.memsci.2008.07.004 1:CAS:528:DC%2BD1cXhtVCgu73E
Talanova, G.G., Talanov, V.S., Gorbunova, M.G., Hwang, H.S., Bartsch, R.A., (2002) J Chem Soc Perkin Trans, 2 (12), pp. 2072-2077
Vogel, A.I., (1961) Quantitative Inorganic Analysis, , Longmans London
Gans, P., Sabatini, A., Vacca, A., (1996) Talanta, 43, pp. 1739-1753. , 10.1016/0039-9140(96)01958-3 1:CAS:528:DyaK28XlvVWrsb0%3D
Lide, D.R., (1990) Handbook of Chemistry and Physics, , 71 CRC Boston
Pearson, R.G., (1963) J Am Chem Soc, 85, pp. 3533-3543. , 10.1021/ja00905a001 1:CAS:528:DyaF2cXksV0%3D
Harris, D., (2007) Quantitative Chemical Analysis, , 7 Freeman New York Section 5-2
Babic, S., Horvat, A.J.M., Pavlovic, D.M., Kastelan-Macan, M., (2007) Trends Anal Chem, 26, pp. 1043-1061. , 10.1016/j.trac.2007.09.004 1:CAS:528:DC%2BD2sXhtlynsbjP
Fernandez, F.A., Bartsch, R.A., Arnaud-Neu, F., Hubscher-Bruder, V., Michel, S., (2010) ARKIVOC, 7, pp. 191-202
Metivier, R., Leray, I., Valeur, B., (2004) Chem Eur J, 10, pp. 4480-4490. , 10.1002/chem.200400259 1:CAS:528:DC%2BD2cXotFyqt74%3D
Bhalla, V., Kumar, R., Kumar, M., Dhir, A., (2007) Tetrahedron, 63, pp. 11153-11159. , 10.1016/j.tet.2007.08.021 1:CAS:528:DC%2BD2sXhtFSisLbL
Hutchinson, T. C., Meema, K. M., (1987) Lead, Mercury, Cadmium and Arsenic in the Environment, , Wiley New Yor
Gadd, G. M., Heavy metal pollutants: Environmental and biotechnological aspects (2000) Encyclopedia of Microbiology, , J. Lederberg (eds). 2 Academic San Diego
Ferguson, J. E., (1990) The Heavy Elements: Environmental Impact and Health Effects, , Pergamon Oxford
Boening, D. W., (2000) Chemosphere, 40, pp. 1335-1351. , 10. 1016/S0045-6535 (99) 00283-0 1: CAS: 528: DC%2BD3cXit1yru7k%3D
Harris, H. H., Pickering, I. J., George, G. N., (2003) Science, 301, p. 1203. , 10. 1126/science. 1085941 1: CAS: 528: DC%2BD3sXmvFejurs%3D
Selid, P. D., Xu, H., Collins, E. M., Striped Face-Collins, M., Zhao, J. X., (2009) Sensors, 9, pp. 5446-5459. , 10. 3390/s90705446 1: CAS: 528: DC%2BD1MXoslSlsL0%3D
Nolan, E. M., Lippard, S. J., (2008) Chem Rev, 108, pp. 3443-3480. , 10. 1021/cr068000q 1: CAS: 528: DC%2BD1cXovFygurY%3D
Talanova, G. G., Hwang, H. S., Talanov, V. S., Bartsch, R. A., (1998) J Chem Soc Chem Commun, pp. 1329-1330
Talanova, G. G., Talanov, V. S., Gorbunova, M. G., Hwang, H. S., Bartsch, R. A., (2002) J Chem Soc Perkin Trans, 2 (12), pp. 2072-2077
Vogel, A. I., (1961) Quantitative Inorganic Analysis, , Longmans London
Lide, D. R., (1990) Handbook of Chemistry and Physics, , 71 CRC Boston
Pearson, R. G., (1963) J Am Chem Soc, 85, pp. 3533-3543. , 10. 1021/ja00905a001 1: CAS: 528: DyaF2cXksV0%3D
Fernandez, F. A., Bartsch, R. A., Arnaud-Neu, F., Hubscher-Bruder, V., Michel, S., (2010) ARKIVOC, 7, pp. 191-202
Selective sensing of Hg2+ by a proton-ionizable calix[4]arene fluoroionophore
A fluorogenic derivative of a calix[4]arene with two proton-ionizable N-(phenyl)sulfonyl carboxamide-containing side arms in the 1,3-positions on the lower rim is employed for the selective sensing of Hg2+ at low concentration levels in water/MeCN (1:1, v/v) solutions containing Pb 2+ and Cd2+. All three metal ions quench the fluorescence of the ligand in pure MeCN. However, in water/MeCN mixed solvent, the recognition of such cations occurs differently as only Hg2+ complexation quenches the fluorescence of the calixarene. Experiments carried out in the presence of an acid and a bulky non-complexing cation shows that the quenching of the calixarene fluorescence upon Hg2+ addition is likely due to proton displacement from the proton-ionizable side arms of the ligand. The system may be employed as a simple tool for the selective and efficient mercury sensing in mixed water/organic solvent. © 2012 Springer-Verlag.
A fluorogenic derivative of a calix[4]arene with two proton-ionizable N-(phenyl)sulfonyl carboxamide-containing side arms in the 1,3-positions on the lower rim is employed for the selective sensing of Hg2+ at low concentration levels in water/MeCN (1:1, v/v) solutions containing Pb 2+ and Cd2+. All three metal ions quench the fluorescence of the ligand in pure MeCN. However, in water/MeCN mixed solvent, the recognition of such cations occurs differently as only Hg2+ complexation quenches the fluorescence of the calixarene. Experiments carried out in the presence of an acid and a bulky non-complexing cation shows that the quenching of the calixarene fluorescence upon Hg2+ addition is likely due to proton displacement from the proton-ionizable side arms of the ligand. The system may be employed as a simple tool for the selective and efficient mercury sensing in mixed water/organic solvent. © 2012 Springer-Verlag.
Selective sensing of Hg2+ by a proton-ionizable calix[4]arene fluoroionophore
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Selective sensing of Hg2+ by a proton-ionizable calix[4]arene fluoroionophore
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8 Records (8 excluding Abstracts).
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Total impact factor: 32.515 (32.515 excluding Abstracts).
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