On the trade-off between processability and opto-electronic properties of single wall carbon nanotube derivatives in thin film heterojunctions
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On the trade-off between processability and opto-electronic properties of single wall carbon nanotube derivatives in thin film heterojunctions (303 views)

Salice P, Sartorio C, Burlini A, Improta R, Pignataro B, Menna E

J Mater Chem C (ISSN: 2050-7526), 2015; 3(2): 303-312.

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Paper type: Journal Article,

Impact factor: 5.066, 5-year impact factor: 5.076

Url: http://www.scopus.com/inward/record.url?eid=2-s2.0-84916899589&partnerID=40&md5=2cfbc2c55471991cc3cd53d381a2946f

Keywords: Carbon, Economic And Social Effects, Electronic Properties, Heterojunctions, Thermogravimetric Analysis, Thin Films, Yarn, Degree Of Functionalization, Density Of Defects, Dft Calculation, Optoelectronic Properties, Poly-3-Hexylthiophene, Soluble Fraction, Thermal Annealing Process, Single-Walled Carbon Nanotubes (swcn),

Affiliations:
*** IBB - CNR ***

Università di Padova, Dipartimento di Scienze Chimiche, Via Marzolo 1Padova, Italy
Università di Palermo, Dipartimento di Fisica e Chimica V.le Delle Scienze, Parco d'Orleans IIPalermo, Italy
Consiglio Nazionale Delle Ricerche, Istituto di Biostrutture e Bioimmagini (IBB-CNR), Via Mezzocannone 16Napoli, Italy
Universit di Padova, Dipartimento di Scienze Chimiche, Via Marzolo 1Padova, Italy
Universit di Palermo, Dipartimento di Fisica e Chimica V. le Delle Scienze, Parco d'Orleans IIPalermo, Italy


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On the trade-off between processability and opto-electronic properties of single wall carbon nanotube derivatives in thin film heterojunctions

A flow functionalization route has been employed to derivatize single wall carbon nanotubes (SWCNTs) by thienylphenyl groups. The SWCNT derivatives in the most soluble fraction have been characterized by thermogravimetric analysis, DLS analysis, DFT calculations, and UV-vis-NIR, microRaman and IR spectroscopies to study the degree of functionalization, the concentration of SWCNTs in solution, the dimension of the aggregates in solutions, the density of defects, and the presence of the thienylphenyl groups. Thin-film heterojunctions made of SWCNT derivatives and poly(3-hexylthiophene) (P3HT) have been prepared by various methods employing the Langmuir-Schaefer technique, spin-coating and thermal annealing processes. By comparing the batch and the flow functionalizations, a trade-off between solubility, processability and the thin-film opto-electronic properties has been found as a result of the degree of functionalization. © The Royal Society of Chemistry 2015.
On the trade-off between processability and opto-electronic properties of single wall carbon nanotube derivatives in thin film heterojunctions

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On the trade-off between processability and opto-electronic properties of single wall carbon nanotube derivatives in thin film heterojunctions

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Improta R
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Del Guerra A, Bartoli A, Belcari N, Herbert D, Motta A, Vaiano A, Di Domenico G, Sabba N, Moretti E, Zavattini G, Lazzarotti M, Sensi L, Larobina M
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5 Records (5 excluding Abstracts).
Total impact factor: 13.967 (13.967 excluding Abstracts).
Total 5 year impact factor: 15.16 (15.16 excluding Abstracts).

Last modified by Marco Comerci on Sunday 12 July 2020, 13:14:50
303 views. Last view on Sunday 06 October 2024, 10:31:08