Femtosecond study on the isomerization dynamics of NK88. I. Ground-state dynamics after photoexcitation (729 views)
J Chem Phys (ISSN: 0021-9606, 0021-9606print, 0897-690online), 2006 Jul 28; 125(4): 44512-44544.
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Paper type: Abstract, Conference, Research Support, Non-U. S. Gov'T, Journal Article,
Impact factor: 3.247, 5-year impact factor: 3.043
Url: Not available.
Keywords: Ground State, Isomerization, Methanol, Phase Equilibria, Probability Density Function, Cyanines, Molecular Systems, Photoisomerization, Plesset Perturbation Theory Calculations, Molecular Dynamics, Diethyl 2, Thiacyanine, -Diethyl-2, -Thiacyanine, 5 Fluoro 2 Thiocytosine, 5-Fluoro-2-Thiocytosine, Carbocyanine, Drug Derivative, Ethylene Glycol, Anisotropy, Article, Chemical Structure, Chemistry, Computer Program, Conformation, Laser, Light, Methodology, Photochemistry, Spectrophotometry, Statistical Model, Temperature, Thermodynamics, Molecular Conformation, Software, Time Factors, Absorption, Cytosine Analogs, Derivatives Chemistry, Ethylene Glycol Chemistry, Methanol Chemistry, Photochemistry Methods, Carbocyanines Chemistry,
Affiliations:
*** IBB - CNR ***
Physikalisches Institut, Universit t W rzburg, Am Hubland, D-97074 W rzburg, Germany
Istituto di Biostrutture e Biommagini, CNR, via Mezzocannone 6, 1-80134 Napoli, Italy
Istituto per i Processi Chimico-Fisici, CNR, CNR di Pisa, Area della Ricerca, via Moruzzi 1, 1-56124 Pisa, Italy
References:
Not available.
J Chem Phys (ISSN: 0021-9606, 0021-9606print, 0897-690online), 2006 Jul 28; 125(4): 44512-44544.
Export to BibTeX Export to EndNote
Paper type: Abstract, Conference, Research Support, Non-U. S. Gov'T, Journal Article,
Impact factor: 3.247, 5-year impact factor: 3.043
Url: Not available.
Keywords: Ground State, Isomerization, Methanol, Phase Equilibria, Probability Density Function, Cyanines, Molecular Systems, Photoisomerization, Plesset Perturbation Theory Calculations, Molecular Dynamics, Diethyl 2, Thiacyanine, -Diethyl-2, -Thiacyanine, 5 Fluoro 2 Thiocytosine, 5-Fluoro-2-Thiocytosine, Carbocyanine, Drug Derivative, Ethylene Glycol, Anisotropy, Article, Chemical Structure, Chemistry, Computer Program, Conformation, Laser, Light, Methodology, Photochemistry, Spectrophotometry, Statistical Model, Temperature, Thermodynamics, Molecular Conformation, Software, Time Factors, Absorption, Cytosine Analogs, Derivatives Chemistry, Ethylene Glycol Chemistry, Methanol Chemistry, Photochemistry Methods, Carbocyanines Chemistry,
Affiliations:
*** IBB - CNR ***
Physikalisches Institut, Universit t W rzburg, Am Hubland, D-97074 W rzburg, Germany
Istituto di Biostrutture e Biommagini, CNR, via Mezzocannone 6, 1-80134 Napoli, Italy
Istituto per i Processi Chimico-Fisici, CNR, CNR di Pisa, Area della Ricerca, via Moruzzi 1, 1-56124 Pisa, Italy
References:
Not available.
Femtosecond study on the isomerization dynamics of NK88. I. Ground-state dynamics after photoexcitation
Recently, optimal control of a photoisomerization reaction in the liquid phase was demonstrated for the first time on the system 3, 3 (') -diethyl-2, 2 (') -thiacyanine (NK88). Additionally, the class of cyanines to which the molecule NK88 belongs draws a lot of attention in different recent theoretical publications. Therefore, a better understanding of the molecular dynamics of this molecular system is of special interest. Experiments using the femtosecond pump-supercontinuum probe technique with an excitation wavelength of 400 nm and a spectral range from 370 to 620 nm for the probe beam have been performed. In order to analyze the dynamics properly the time window has been chosen to comprise the characteristic times of the contributing processes, additionally we have employed two solvents, methanol and ethylene glycol, and have conducted anisotropy measurements. The spectroscopic data have been assigned to different molecular states with the help of density functional theory and second-order Moller-Plesset perturbation theory calculations. The analysis of the data has revealed in the most likely model that three different isomers exist with different lifetimes. On the basis of experimental and theoretical data, a conclusive scheme of the isomerization reaction is presented. (c) 2006 American Institute of Physics
Recently, optimal control of a photoisomerization reaction in the liquid phase was demonstrated for the first time on the system 3, 3 (') -diethyl-2, 2 (') -thiacyanine (NK88). Additionally, the class of cyanines to which the molecule NK88 belongs draws a lot of attention in different recent theoretical publications. Therefore, a better understanding of the molecular dynamics of this molecular system is of special interest. Experiments using the femtosecond pump-supercontinuum probe technique with an excitation wavelength of 400 nm and a spectral range from 370 to 620 nm for the probe beam have been performed. In order to analyze the dynamics properly the time window has been chosen to comprise the characteristic times of the contributing processes, additionally we have employed two solvents, methanol and ethylene glycol, and have conducted anisotropy measurements. The spectroscopic data have been assigned to different molecular states with the help of density functional theory and second-order Moller-Plesset perturbation theory calculations. The analysis of the data has revealed in the most likely model that three different isomers exist with different lifetimes. On the basis of experimental and theoretical data, a conclusive scheme of the isomerization reaction is presented. (c) 2006 American Institute of Physics
Femtosecond study on the isomerization dynamics of NK88. I. Ground-state dynamics after photoexcitation
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Femtosecond study on the isomerization dynamics of NK88. I. Ground-state dynamics after photoexcitation
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View Export to BibTeX Export to EndNote
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View Export to BibTeX Export to EndNote
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Impact Factor: 7.696
View Export to BibTeX Export to EndNote
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View Export to BibTeX Export to EndNote
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View Export to BibTeX Export to EndNote
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Impact Factor: 20.233
View Export to BibTeX Export to EndNote
Improta R, Barone V
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View Export to BibTeX Export to EndNote
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Proc Electrochem Soc, 2004; 10: 29-32.
Impact Factor: 0
View Export to BibTeX Export to EndNote
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Impact Factor: 3.834
View Export to BibTeX Export to EndNote
Improta R, Kudin KN, Scuseria GE, Barone V
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Impact Factor: 6.201
View Export to BibTeX Export to EndNote
22 Records (18 excluding Abstracts).
Total impact factor: 156.087 (143.618 excluding Abstracts).
Total 5 year impact factor: 196.581 (184.077 excluding Abstracts).
Total impact factor: 156.087 (143.618 excluding Abstracts).
Total 5 year impact factor: 196.581 (184.077 excluding Abstracts).
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