Department of Chemical Science, University of Catania, viale A. Doria, 6, 95125 Catania, Italy
CNR, Ist. di Biostrutture e Bioimmagini, Sezione di Catania, viale A. Doria, 6, 95125 Catania, Italy
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Ligand exchange chiral separations by cyclodextrin derivatives in capillary electrophoresis
A β-cyclodextrin substituted by an imidazole-bound histamine (CDmh) was successfully used to separate underivatised tryptophan racemate in capillary electrophoresis in the presence of copper(II) ion by the ligand exchange mechanism. To the best of our knowledge, this is the first example of a cyciodextrin derivative behaving as the first coordination sphere ligand in the complex added to the background electrolyte (BGE).
Ligand exchange chiral separations by cyclodextrin derivatives in capillary electrophoresis
No results.
Ligand exchange chiral separations by cyclodextrin derivatives in capillary electrophoresis
Kállay C, Dávid A, Timári S, Nagy EM, Sanna D, Garribba E, Micera G, De Bona P, Pappalardo G, Rizzarelli E, Sóvágó I * Copper(II) complexes of rat amylin fragments(357 views) Dalton T (ISSN: 1477-9234, 1477-9226, 1477-9234electronic), 2011 Oct 14; 40(38): 9711-9721. Impact Factor:3.838 ViewExport to BibTeXExport to EndNote